Yalavac Irem, Lyons Sarah E, Webb Michael R, Procter David J
School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Chem Commun (Camb). 2014 Nov 4;50(85):12863-6. doi: 10.1039/c4cc05404k.
The SmI2-H2O reagent system mediates challenging 5-exo/6-exo lactone radical cascade cyclisations that deliver carbo[5.4.0]bicyclic motifs in a diastereoselective, one-pot process that establish two new carbocyclic rings and four stereocentres.
SmI2-H2O试剂体系介导具有挑战性的5-外向/6-外向内酯自由基级联环化反应，该反应在一个非对映选择性的一锅法过程中生成碳[5.4.0]双环基序，构建两个新的碳环和四个立体中心。
