Sun Kai, Wang Xin, Li Gang, Zhu Zhonghong, Jiang Yongqing, Xiao Beibei
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China.
Chem Commun (Camb). 2014 Nov 4;50(85):12880-3. doi: 10.1039/c4cc06003b.
An intermolecular oxidative C-N formation reaction of aryl ethers with pharmacological saccharins was realized under metal-free conditions for the first time. The understanding of the intrinsic characteristics between C(sp(3))-H and C(sp(2))-O bonds of aryl ethers and their potential for application might promote more research interest in this area.
首次在无金属条件下实现了芳基醚与药用糖精的分子间氧化C-N形成反应。了解芳基醚的C(sp(3))-H键和C(sp(2))-O键之间的内在特性及其应用潜力，可能会激发该领域更多的研究兴趣。
