Huang Pei-Hsing, Jhan Jhih-Wei, Cheng Yi-Ming, Cheng Hau-Hsein
Department of Mechanical Engineering, National Pingtung University of Science and Technology, Pingtung 912, Taiwan.
ScientificWorldJournal. 2014;2014:937867. doi: 10.1155/2014/937867. Epub 2014 Aug 13.
This study experimentally analyzed the carbon dioxide adsorption capacity of Moso-bamboo- (Phyllostachys edulis-) based porous charcoal. The porous charcoal was prepared at various carbonization temperatures and ground into powders with 60, 100, and 170 meshes, respectively. In order to understand the adsorption characteristics of porous charcoal, its fundamental properties, namely, charcoal yield, ash content, pH value, Brunauer-Emmett-Teller (BET) surface area, iodine number, pore volume, and powder size, were analyzed. The results show that when the carbonization temperature was increased, the charcoal yield decreased and the pH value increased. Moreover, the bamboo carbonized at a temperature of 1000(°)C for 2 h had the highest iodine sorption value and BET surface area. In the experiments, charcoal powders prepared at various carbonization temperatures were used to adsorb 1.854% CO2 for 120 h. The results show that the bamboo charcoal carbonized at 1000(°)C and ground with a 170 mesh had the best adsorpt on capacity, significantly decreasing the CO2 concentration to 0.836%. At room temperature and atmospheric pressure, the Moso-bamboo-based porous charcoal exhibited much better CO2 adsorption capacity compared to that of commercially available 350-mesh activated carbon.
本研究对毛竹基多孔炭的二氧化碳吸附性能进行了实验分析。在不同的炭化温度下制备多孔炭,并分别研磨成60目、100目和170目的粉末。为了解多孔炭的吸附特性,对其基本性质进行了分析,包括炭产率、灰分含量、pH值、比表面积(BET)、碘值、孔容和粉末粒度。结果表明,随着炭化温度的升高,炭产率降低,pH值升高。此外,在1000℃下炭化2小时的竹炭碘吸附值和BET比表面积最高。在实验中,使用不同炭化温度制备的炭粉吸附1.854%的二氧化碳,吸附时间为120小时。结果表明,在1000℃下炭化并研磨成170目的竹炭吸附能力最佳,可将二氧化碳浓度显著降低至0.836%。在室温和大气压下,毛竹基多孔炭的二氧化碳吸附能力比市售350目的活性炭要好得多。