甲亚胺亚胺的高度对映选择性膦化和氢膦酰化反应：使用手性方酰胺作为氢键有机催化剂。
Highly enantioselective phosphination and hydrophosphonylation of azomethine imines: using chiral squaramide as a hydrogen bonding organocatalyst.
作者信息
Kong Ling-Pei, Li Nai-Kai, Zhang Shao-Yun, Chen Xiang, Zhao Min, Zhang Ya-Fei, Wang Xing-Wang
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.
出版信息
Org Biomol Chem. 2014 Nov 21;12(43):8656-70. doi: 10.1039/c4ob01472c.
Enantioselective phosphination and hydrophosphonylation reactions between azomethine imines and diarylphosphine oxides or dialkyl phosphites were respectively developed by the use of a chiral squaramide as the hydrogen bonding organocatalyst, which afforded two types of phosphorus containing product in high yields with good to excellent enantioselectivities.
通过使用手性方酰胺作为氢键有机催化剂，分别开发了甲亚胺亚胺与二芳基氧化膦或亚磷酸二烷基酯之间的对映选择性磷化反应和氢膦酰化反应，以高收率和良好至优异的对映选择性得到了两种含磷产物。
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