Jones Matthew D
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY UK.
Chem Cent J. 2014 Sep 10;8(1):53. doi: 10.1186/s13065-014-0053-4. eCollection 2014.
1,3-Butadiene is an important constituent of many products that we rely upon. It is currently prepared from non-sustainably derived sources. However, in the early part of the 20(th) Century the use of ethanol as a source of 1,3-butadiene has been reported. With the arrival of a cheap and bountiful supply of crude-oil derived sources the need for the sustainable route was deemed unnecessary. In recent years the conversion of ethanol to 1,3-butadiene has undergone somewhat of a mini resurgence as the chemical industry looks to try to find a sustainable and secure route to this important building block. This review will emphasise some of the most recent work in the field and look ahead to what needs to be achieved to make this research a reality. Graphical AbstractThis review focusses on the recent progress in the area of the conversion of ethanol to 1, 3-butadiene.
1,3 - 丁二烯是我们所依赖的许多产品的重要成分。它目前由不可持续的来源制备。然而，在20世纪早期，已有使用乙醇作为1,3 - 丁二烯来源的报道。随着原油衍生来源的廉价且丰富供应的出现，可持续路线的需求被认为没有必要。近年来，随着化学工业试图找到通往这种重要基础原料的可持续且可靠的路线，乙醇向1,3 - 丁二烯的转化有所复兴。本综述将强调该领域的一些最新研究工作，并展望要使这项研究成为现实还需要实现什么。图形摘要本综述聚焦于乙醇转化为1,3 - 丁二烯领域的最新进展。
