Das Partha Pratim, Devi Parukuttyamma Sujatha
Nano-Structured Materials Division, Council of Scientific & Industrial Research (CSIR)-Central Glass and Ceramic Research Institute , Kolkata 700032, India.
Inorg Chem. 2014 Oct 20;53(20):10797-9. doi: 10.1021/ic501598h. Epub 2014 Oct 6.
In this Communication, we report a facile approach to synthesize a technologically important oxide Zn2SnO4 (ZTO) by a temperature-dependent solid-state reaction without the Kirkendall effect. Single-phase defect-free ZTO was formed upon calcination of a homogeneous 2:1 mixture of reactive ZnO rods and SnO2 nanoparticles at 1000 °C. We also observed interesting photocatalytic and photovoltaic properties from the synthesized ZTO material.
在本通讯中，我们报道了一种简便的方法，通过温度依赖性固态反应合成一种具有重要技术意义的氧化物Zn2SnO4（ZTO），且不存在柯肯达尔效应。将反应性ZnO棒和SnO2纳米颗粒以2:1的均匀混合物在1000°C下煅烧后，形成了单相无缺陷的ZTO。我们还从合成的ZTO材料中观察到了有趣的光催化和光伏特性。
