Wang Hong, Sofer Zdeněk, Eng Alex Yong Sheng, Pumera Martin
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore).
Chemistry. 2014 Nov 10;20(46):14946-50. doi: 10.1002/chem.201404238. Epub 2014 Oct 7.
A novel concept of an iridium-based bubble-propelled Janus-particle-type graphene micromotor with very high surface area and with very low catalyst loading is described. The low loading of Ir catalyst (0.54 at %) allows for fast motion of graphene microparticles with high surface area of 316.2 m(2) g(-1). The micromotor was prepared with a simple and scalable method by thermal exfoliation of iridium-doped graphite oxide precursor composite in hydrogen atmosphere. Oxygen bubbles generated from the decomposition of hydrogen peroxide at the iridium catalytic sites provide robust propulsion thrust for the graphene micromotor. The high surface area and low iridium catalyst loading of the bubble-propelled graphene motors offer great possibilities for dramatically enhanced cargo delivery.
描述了一种基于铱的气泡驱动的具有非常高表面积和非常低催化剂负载的双面粒子型石墨烯微电机的新颖概念。铱催化剂的低负载量(0.54 at %)使得具有316.2 m(2) g(-1)高表面积的石墨烯微粒能够快速移动。通过在氢气气氛中对铱掺杂氧化石墨前驱体复合材料进行热剥离,采用简单且可扩展的方法制备了该微电机。在铱催化位点上过氧化氢分解产生的氧气气泡为石墨烯微电机提供了强大的推进推力。气泡驱动的石墨烯电机的高表面积和低铱催化剂负载量为显著增强货物运输提供了巨大可能性。