Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , Singapore 637371, Singapore.
J Am Chem Soc. 2014 Feb 19;136(7):2719-22. doi: 10.1021/ja411705d. Epub 2014 Feb 7.
Autonomous bubble-propelled catalytic micro- and nanomachines show great promise in the fields of biomedicine, environmental science, and natural resources. It is envisioned that thousands and millions of such micromachines will swarm and communicate with each other, performing desired actions. To date, mainly platinum catalyst surfaces have been used for the decomposition of a fuel, hydrogen peroxide, to oxygen bubbles. Here we propose Pt-free, low-cost inorganic catalysts for powering micromotors based on silver and manganese dioxide surfaces. Such Ag- and MnO2-based bubble-powered micromotors show fast motion even at very low concentrations of fuel, down to 0.1% of H2O2. These catalysts should enable unparalleled widespread use of such motors in real applications, as it will be possible to make them in large quantities at low cost.
自主气泡推进的催化微纳机器在生物医药、环境科学和自然资源等领域有很大的应用前景。人们设想,成千上万的这种微型机器将进行群体协作和相互通信,执行预期的动作。迄今为止,主要使用铂催化剂表面来分解燃料过氧化氢以产生氧气气泡。在这里,我们提出了基于银和二氧化锰表面的无铂、低成本无机催化剂,为基于气泡的微型发动机提供动力。基于 Ag 和 MnO2 的气泡动力微型发动机即使在非常低浓度的燃料(低至 0.1%的 H2O2)下也能快速运动。这些催化剂将使这些发动机能够在实际应用中得到前所未有的广泛应用,因为可以以低成本大量制造它们。