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将壳层隔离纳米粒子增强拉曼光谱方法扩展至单晶电极表面的界面离子液体。

Extending the shell-isolated nanoparticle-enhanced Raman spectroscopy approach to interfacial ionic liquids at single crystal electrode surfaces.

作者信息

Zhang Meng, Yu Li-Juan, Huang Yi-Fan, Yan Jia-Wei, Liu Guo-Kun, Wu De-Yin, Tian Zhong-Qun, Mao Bing-Wei

机构信息

State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

Chem Commun (Camb). 2014 Dec 7;50(94):14740-3. doi: 10.1039/c4cc06269h.

DOI:10.1039/c4cc06269h
PMID:25325083
Abstract

We employ, for the first time, a shell-isolated nanoparticle-enhancement strategy to extend Raman spectroscopy studies to single crystal electrode surfaces in ionic liquids, and combine density functional theory (DFT) calculations to elucidate the structural details of the imidazolium-based ionic liquid-Au single crystal electrode interfaces.

摘要

我们首次采用壳层隔离纳米粒子增强策略,将拉曼光谱研究扩展到离子液体中的单晶电极表面,并结合密度泛函理论(DFT)计算来阐明基于咪唑鎓的离子液体-金单晶电极界面的结构细节。

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