Dong Jinqiao, Liu Yan, Cui Yong
School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.
Chem Commun (Camb). 2014 Dec 11;50(95):14949-52. doi: 10.1039/c4cc07648f.
Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF- is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.
制备了三种基于手性稳健二烯的多孔有机框架（POF）。POF-经金属化后被证明是一种高效的非均相催化剂，用于不对称共轭加成时对映体过量值高达93%，并且它还可以作为一种新型手性固定相用于外消旋体的气相色谱分离。
