Asymmetric -Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity.
作者信息
Vora Harit U, Rovis Tomislav
机构信息
Department of Chemistry, Colorado State University, Fort Collins CO, 80523.
出版信息
Aldrichimica Acta. 2011;44(1):3-11.
Abstract
摘要
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Carbene catalysts.卡宾催化剂
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N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes.N-杂环卡宾催化的串联反应，涉及未活化炔烃的加氢酰化反应。
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N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids.N-杂环卡宾催化的不对称水合反应：直接合成α-手性和α-氘代、α-氯代和α-氟代羧酸。
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