Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China).
Angew Chem Int Ed Engl. 2015 Jan 2;54(1):231-5. doi: 10.1002/anie.201408201. Epub 2014 Nov 4.
An interface microenvironment between nanocarbon and ionic liquids (ILs) is presented. By an entrapping effect, a few layers of ILs can be finely deposited on the surface of nanocarbon, endowing amazingly tailorable surface properties. The entrapped IL layer, which was believed to be unable to be charred under pyrolysis conditions alone, can be further carbonized to a functional carbon layer. C, B, and N were confirmed to share the same hexagonal ring in the resultant layer, which provides more designable electronic properties.
呈现了纳米碳与离子液体（ILs）之间的界面微环境。通过包埋效应，可以将数层 IL 精细地沉积在纳米碳的表面上，赋予其惊人的可调节表面性能。被认为在单独的热解条件下无法碳化的包埋 IL 层可以进一步碳化形成功能性碳层。在所得层中证实 C、B 和 N 共享相同的六元环，这为其提供了更多可设计的电子特性。
