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在秸秆浆厂内对废弃小麦秸秆进行自水解预处理以生产纤维素乙醇

Autohydrolysis pretreatment of waste wheat straw for cellulosic ethanol production in a co-located straw pulp mill.

作者信息

Han Qiang, Jin Yanbin, Jameel Hasan, Chang Hou-Min, Phillips Richard, Park Sunkyu

机构信息

Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695, USA,

出版信息

Appl Biochem Biotechnol. 2015 Jan;175(2):1193-210. doi: 10.1007/s12010-014-1349-5. Epub 2014 Nov 6.

Abstract

Waste wheat straw (WWS) is the waste product from feedstock preparation process in a straw pulp mill. It has a significant annual production rate and no commercial value has been explored on this material. In this study, waste wheat straw was pretreated using an autohydrolysis process followed by mechanical refining, and the pretreated materials were further enzymatically hydrolyzed to evaluate the total sugar recovery for bioethanol production. Results show that autohydrolysis at 170 °C for 40 min followed by 6000 revolution PFI refining provided the best result in this study, where a total sugar recovery (total sugars in autohydrolysis filtrate and enzymatic hydrolyzate over total carbohydrates on raw WWS) of 70 % at 4 filter paper unit per oven dry gram (FPU/OD g) substrate enzyme charge could be obtained. The economic evaluation of this biorefinery process indicates that cellulosic ethanol production from autohydrolysis of WWS is a very profitable business, with 28.4 % of internal rate of return can be achieved based on current ethanol wholesale price in China.

摘要

废弃麦秸(WWS)是草浆造纸厂原料制备过程中的废弃物。其年产量可观,但尚未对该材料进行商业价值开发。在本研究中,采用自水解工艺对废弃麦秸进行预处理,随后进行机械精磨,并对预处理后的材料进一步进行酶水解,以评估生物乙醇生产中的总糖回收率。结果表明,在本研究中,170℃下自水解40分钟,随后以6000转的PFI精磨效果最佳,在每克烘干底物4滤纸单位(FPU/OD g)的酶用量下,总糖回收率(自水解滤液和酶水解产物中的总糖占原始WWS中总碳水化合物的比例)可达70%。该生物精炼过程的经济评估表明,通过WWS自水解生产纤维素乙醇是一项非常有利可图的业务,根据中国目前的乙醇批发价格,内部收益率可达28.4%。

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