Wan Decheng, Chen Feng, Geng Qingrui, Lu Hang, Willcock Helen, Liu Qiuming, Wang Fangyingkai, Zou Kaidian, Jin Ming, Pu Hongting, Du Jianzhong
School of Materials Science and Engineering, Tongji University, 4800 Caoan Road, Shanghai 210804, PR China.
Department of Chemistry, Gibbet Hill Road, University of Warwick, CV4 7AL, UK.
Sci Rep. 2014 Dec 3;4:7296. doi: 10.1038/srep07296.
The efficient removal of trace carcinogenic organic pollutants, such as polycyclic aromatic hydrocarbons (PAHs) and ionic dyes, from water is an important technical challenge. We report a highly effective recyclable multifunctional azobenzene (AZ)-based silica-supported polymeric adsorbent which can simultaneously remove both PAHs and anionic dyes from water to below parts per billion (ppb) level based on multiple interactions such as the hydrophobic effect, π-π stacking and electrostatic interactions, thus providing a new strategy for designer water remediation materials.
从水中有效去除痕量致癌有机污染物,如多环芳烃(PAHs)和离子染料,是一项重要的技术挑战。我们报道了一种高效可回收的基于多功能偶氮苯(AZ)的二氧化硅负载聚合物吸附剂,它基于疏水作用、π-π堆积和静电相互作用等多种相互作用,能同时将水中的PAHs和阴离子染料去除至十亿分之一(ppb)水平以下,从而为设计型水修复材料提供了一种新策略。