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Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species.

作者信息

Martin Daniel J, McCarthy Brian D, Donley Carrie L, Dempsey Jillian L

机构信息

Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA.

出版信息

Chem Commun (Camb). 2015 Mar 28;51(25):5290-3. doi: 10.1039/c4cc08662g.

DOI:10.1039/c4cc08662g
PMID:25470993
Abstract

A Ni(II) complex degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen. Comparison with a similar compound permitted investigation of the degradation mechanism.

摘要

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