Crystal structure of nitrido[5,10,15,20-tetra-kis(4-methylphenyl)-porphyrinato]-manganese(V).
作者信息
Shields Mason R, Guzei Ilia A, Goll James G
机构信息
Department of Chemistry, Geoscience, and Physics, 1000 Edgewood College Drive, Edgewood College, Madison, WI 53711, USA.
Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI 53706, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 24;70(Pt 10):242-5. doi: 10.1107/S1600536814020558. eCollection 2014 Oct 1.
The title compound, [Mn(C48H36N4)(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom and the nitride N atom are equally disordered across the inversion center. The Mn N distance is 1.516 (4) Å. The Mn(V) atom is displaced from the plane defined by the four equatorial nitro-gen atoms toward the nitride ligand by 0.3162 (6) Å.
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