Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel.
Inorg Chem. 2013 Aug 19;52(16):9349-55. doi: 10.1021/ic400918d. Epub 2013 Aug 6.
The synthesis and characterization of manganese complexes of 5,10,15-tris(4-nitrophenyl) corrole in different oxidation states are described. Adoption of established protocols for the synthesis of (nitrido)manganese(V) complexes led to the expected corrole derivative as a minor product, accompanied by nitrogen atom insertion into the macrocycle. The major product was fully characterized via the combination of spectroscopy and X-ray crystallography as (nitrido)manganese(V) 6-azahemiporphycene.
本文描述了不同氧化态下 5,10,15-三(4-硝基苯基)卟啉锰配合物的合成与表征。采用已建立的合成（亚硝酰基）锰（V）配合物的方案，得到了预期的卟啉衍生物作为次要产物，同时伴随着氮原子插入大环。主要产物通过光谱和 X 射线晶体学的组合进行了充分的表征，结果为（亚硝酰基）锰（V）六氮杂半卟啉。
