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用作传感器快速测定猪肉中莱克多巴胺残留量的莱克多巴胺-四苯基硼酸盐复合纳米粒子的制备

Preparation of ractopamine-tetraphenylborate complexed nanoparticles used as sensors to rapidly determine ractopamine residues in pork.

作者信息

Zhang Jing, Shao Xintian, Yue Jingli, Li Donghui, Chen Zhenhua

机构信息

College of Pharmacy, Liaoning Medical University, Jinzhou 121001, People's Republic of China.

出版信息

Nanoscale Res Lett. 2014 Nov 27;9(1):639. doi: 10.1186/1556-276X-9-639. eCollection 2014.

Abstract

In this work, we reported a simple, fast, and sensitive determination of ractopamine (RAC) residues in pork by using novel ractopamine-tetraphenylborate complexed nanoparticles (RT NPs) as sensors. The prepared RT NPs exhibited a fast response time of 10 s, a wide linear range from 0.1 to 1.0 × 10(-7) mol/L, and a very low detection limit of 7.4 × 10(-8) mol/L. The prepared sensor also presents a high selectivity for ractopamine under different pH conditions ranged from 2.85 to 7.18. These results reveal that the fabricated RT NPs can be used as efficient electrochemical sensors to determine ractopamine in animal productions.

摘要

在本研究中,我们报道了一种简单、快速且灵敏的方法,通过使用新型的莱克多巴胺 - 四苯基硼酸盐复合纳米粒子(RT NPs)作为传感器来测定猪肉中的莱克多巴胺(RAC)残留量。制备的RT NPs响应时间快,仅需10秒,线性范围宽,为0.1至1.0×10⁻⁷ mol/L,检测限极低,为7.4×10⁻⁸ mol/L。所制备的传感器在pH值范围为2.85至7.18的不同条件下,对莱克多巴胺也具有高选择性。这些结果表明,所制备的RT NPs可作为高效的电化学传感器用于测定动物产品中的莱克多巴胺。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6d0/4256977/c4351e6056e0/1556-276X-9-639-1.jpg

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