Department of Environmental Engineering, Kocaeli University, 41380, Kocaeli, Turkey.
Department of Environmental Engineering, Akdeniz University, 07058, Antalya, Turkey.
Environ Sci Pollut Res Int. 2015 Oct;22(19):14537-45. doi: 10.1007/s11356-014-3924-2. Epub 2014 Dec 17.
Perfluorooctane sulfonic acid (PFOS) and related substances have been listed as persistent organic pollutants (POPs) in the Stockholm Convention. Countries which have ratified the Convention need to take appropriate actions to control PFOS use and release. This study compiles and enhances the findings of the first inventory of PFOS and related substances use in Turkey conducted within the frame of the Stockholm Convention National Implementation Plan (NIP) update. The specific Harmonized Commodity Description and Coding System (Harmonized System (HS)) codes of imported and exported goods that possibly contain PFOS and 165 of Chemical Abstracts Service (CAS) numbers of PFOS-related substances were assessed for acquiring information from customs and other authorities. However, with the current approaches available, no useful information could be compiled since HS codes are not specific enough and CAS numbers are not used by customs. Furthermore, the cut-off volume in chemical databases in Turkey and the reporting limit in the HS system (0.1 %) are too high for controlling PFOS. The attempt of modeling imported volumes by a Monte Carlo simulation did not also result in a satisfactory estimate, giving an upper-bound estimate above the global production volumes. The replies to questionnaires were not satisfactory, highlighting that an elaborated approach is needed in the communication with potentially PFOS-using stakeholders. The experience of the challenges of gathering information on PFOS in articles and products revealed the gaps of controlling highly hazardous substances in products and articles and the need of improvements.
全氟辛烷磺酸(PFOS)和相关物质已被列入《斯德哥尔摩公约》持久性有机污染物(POPs)。批准该公约的国家需要采取适当行动,控制 PFOS 的使用和释放。本研究对土耳其根据《斯德哥尔摩公约国家实施计划》(NIP)更新进行的首次全氟辛烷磺酸和相关物质使用情况清查的结果进行了汇编和补充。评估了进口和出口可能含有 PFOS 的货物的特定协调商品描述和编码制度(协调制度(HS))编码以及 165 种全氟辛烷磺酸相关物质的化学文摘社(CAS)编号,以便从海关和其他主管部门获取信息。然而,由于目前采用的方法无法获得有用的信息,因为 HS 编码不够具体,海关不使用 CAS 编号。此外,土耳其化学数据库中的截止体积和 HS 系统中的报告限值(0.1%)对于控制 PFOS 来说过高。通过蒙特卡罗模拟对进口量进行建模的尝试也没有得出令人满意的估计,给出的上限估计值高于全球生产量。对调查问卷的答复并不令人满意,这突出表明需要在与潜在使用 PFOS 的利益攸关方进行沟通时采用更详细的方法。在收集关于物品和产品中 PFOS 信息方面遇到的挑战的经验揭示了在产品和物品中控制高度危险物质方面的差距以及需要改进的地方。