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从新西兰麦卢卡花(Leptospermum scoparium)的花蜜中分离出麦芽醇葡萄糖苷。

Isolation of maltol glucoside from the floral nectar of New Zealand mānuka (Leptospermum scoparium).

机构信息

Chemistry, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand.

Chemistry, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand.

出版信息

Food Chem. 2015 May 1;174:306-9. doi: 10.1016/j.foodchem.2014.11.073. Epub 2014 Nov 17.

Abstract

Maltol glucoside (3-(β-D-glucopyranosyloxy)-2-methyl-4H-pyran-4-one), 1, was isolated from a preparation of the floral nectar from the New Zealand mānuka tree (Leptospermum scoparium). 1 eluted just after dihydroxyacetone in HPLC of underivatized nectar and showed a UV absorbance maximum of 258 nm. The structure of 1 was confirmed by NMR and high resolution mass spectrometry.

摘要

麦芽酚葡糖苷(3-(β-D-吡喃葡萄糖苷基)-2-甲基-4H-吡喃-4-酮)1 从新西兰茶树(Leptospermum scoparium)的花蜜制剂中分离得到。1 在未衍生的花蜜的 HPLC 中洗脱后正好在二羟丙酮之后,其 UV 吸收最大值为 258nm。通过 NMR 和高分辨率质谱法确定了 1 的结构。

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