由硫连接的N-磺酰基-1,2,3-三唑衍生的氮杂乙烯基类卡宾引发的铑催化的1,2-硫迁移/氮杂-狄尔斯-阿尔德串联反应。
A Rh-catalyzed 1,2-sulfur migration/aza-Diels-Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles.
作者信息
Jiang Yu, Tang Xiang-Ying, Shi Min
机构信息
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road No. 130, Shanghai, 200237, China.
出版信息
Chem Commun (Camb). 2015 Feb 7;51(11):2122-5. doi: 10.1039/c4cc08829h. Epub 2014 Dec 23.
PMID:25536337
Abstract
A novel Rh(ii) catalyzed intramolecular 1,2-sulfur rearrangement/intermolecular aza-Diels-Alder cascade initiated by azavinyl carbenes has been developed, efficiently affording sulfur-containing tetrahydropyridine derivatives or α,β-unsaturated imines with a broad substrate scope.
摘要
已开发出一种由氮杂乙烯基卡宾引发的新型铑（II）催化分子内1,2-硫重排/分子间氮杂狄尔斯-阿尔德串联反应，能高效地提供底物范围广泛的含硫四氢吡啶衍生物或α,β-不饱和亚胺。
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