Fu Yubin, Qiu Feng, Zhang Fan, Mai Yiyong, Wang Yingchao, Fu Shibo, Tang Ruizhi, Zhuang Xiaodong, Feng Xinliang
School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
Chem Commun (Camb). 2015 Mar 28;51(25):5298-301. doi: 10.1039/c4cc08551e.
A new dual-boron-cored luminogen ligated with a nitrogen-containing multidentate ligand and four bulky phenyl rings was readily synthesized. The unique molecular structure endows this BN-containing luminogen with rich photophysical properties in either solution or in the solid state, including a large Stokes shift, aggregation induced emission activity and reversible piezochromism. Furthermore, this BN-containing luminogen exhibits good capabilities for imaging living cells and sensing of fluoride anions.
一种与含氮多齿配体和四个大位阻苯环相连的新型双硼核发光体很容易合成。独特的分子结构赋予这种含硼氮发光体在溶液或固态中都具有丰富的光物理性质,包括大斯托克斯位移、聚集诱导发光活性和可逆压致变色。此外,这种含硼氮发光体在活细胞成像和氟离子传感方面表现出良好的能力。