Song Yanhua, Lei Yucheng, Xu Hui, Wang Cheng, Yan Jia, Zhao Haozhu, Xu Yuanguo, Xia Jiexiang, Yin Sheng, Li Huaming
School of Materials Science & Engineering, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China.
Dalton Trans. 2015 Feb 21;44(7):3057-66. doi: 10.1039/c4dt03242j.
Novel few-layer MoS2/Ag3PO4 composites were fabricated. The results indicated that Ag3PO4 nanoparticles were directly formed on the surface of few-layer MoS2. The physical and chemical properties of the few-layer MoS2/Ag3PO4 composite photocatalysts were tested in order to investigate the effects of few-layer MoS2 on the photocatalytic activity of Ag3PO4. The photocatalytic activity of the few-layer MoS2/Ag3PO4 composites was evaluated by the photocatalytic degradation of Rhodamine B (RhB) and bisphenol A (BPA) under visible light irradiation. The photocatalytic activity of the few-layer MoS2/Ag3PO4 composites was higher than that of pure Ag3PO4. The optimal few-layer MoS2 content for the organic pollutant degradation of the heterojunction structures was determined. The synergic effect between few-layer MoS2 and Ag3PO4 was found to lead to an improved photogenerated carrier separation. The stability and the possible photocatalytic mechanism of the composites were also discussed.
制备了新型的少层MoS2/Ag3PO4复合材料。结果表明,Ag3PO4纳米颗粒直接形成在少层MoS2的表面。测试了少层MoS2/Ag3PO4复合光催化剂的物理和化学性质,以便研究少层MoS2对Ag3PO4光催化活性的影响。通过在可见光照射下对罗丹明B(RhB)和双酚A(BPA)的光催化降解来评估少层MoS2/Ag3PO4复合材料的光催化活性。少层MoS2/Ag3PO4复合材料的光催化活性高于纯Ag3PO4。确定了异质结结构对有机污染物降解的最佳少层MoS2含量。发现少层MoS2与Ag3PO4之间的协同效应导致光生载流子分离得到改善。还讨论了复合材料的稳定性和可能的光催化机理。