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用于增强光催化活性的少层MoS₂纳米片负载Ag₃PO₄的合成

Synthesis of few-layer MoS2 nanosheet-loaded Ag3PO4 for enhanced photocatalytic activity.

作者信息

Song Yanhua, Lei Yucheng, Xu Hui, Wang Cheng, Yan Jia, Zhao Haozhu, Xu Yuanguo, Xia Jiexiang, Yin Sheng, Li Huaming

机构信息

School of Materials Science & Engineering, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China.

出版信息

Dalton Trans. 2015 Feb 21;44(7):3057-66. doi: 10.1039/c4dt03242j.

Abstract

Novel few-layer MoS2/Ag3PO4 composites were fabricated. The results indicated that Ag3PO4 nanoparticles were directly formed on the surface of few-layer MoS2. The physical and chemical properties of the few-layer MoS2/Ag3PO4 composite photocatalysts were tested in order to investigate the effects of few-layer MoS2 on the photocatalytic activity of Ag3PO4. The photocatalytic activity of the few-layer MoS2/Ag3PO4 composites was evaluated by the photocatalytic degradation of Rhodamine B (RhB) and bisphenol A (BPA) under visible light irradiation. The photocatalytic activity of the few-layer MoS2/Ag3PO4 composites was higher than that of pure Ag3PO4. The optimal few-layer MoS2 content for the organic pollutant degradation of the heterojunction structures was determined. The synergic effect between few-layer MoS2 and Ag3PO4 was found to lead to an improved photogenerated carrier separation. The stability and the possible photocatalytic mechanism of the composites were also discussed.

摘要

制备了新型的少层MoS2/Ag3PO4复合材料。结果表明,Ag3PO4纳米颗粒直接形成在少层MoS2的表面。测试了少层MoS2/Ag3PO4复合光催化剂的物理和化学性质,以便研究少层MoS2对Ag3PO4光催化活性的影响。通过在可见光照射下对罗丹明B(RhB)和双酚A(BPA)的光催化降解来评估少层MoS2/Ag3PO4复合材料的光催化活性。少层MoS2/Ag3PO4复合材料的光催化活性高于纯Ag3PO4。确定了异质结结构对有机污染物降解的最佳少层MoS2含量。发现少层MoS2与Ag3PO4之间的协同效应导致光生载流子分离得到改善。还讨论了复合材料的稳定性和可能的光催化机理。

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