Aijaz Arshad, Zhu Qi-Long, Tsumori Nobuko, Akita Tomoki, Xu Qiang
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
Chem Commun (Camb). 2015 Feb 14;51(13):2577-80. doi: 10.1039/c4cc09139f.
Surfactant-free Pd nanoparticles, immobilized to a metal-organic framework (MIL-101), have been used for the first time as highly active and durable catalysts in water for biomass refining (hydrodeoxygenation of vanillin, a typical compound of lignin) with metal nanoparticle size- and location-dependent catalytic activity and selectivity.
固定在金属有机框架（MIL-101）上的无表面活性剂钯纳米颗粒，首次被用作水中生物质精炼（香草醛的加氢脱氧，木质素的一种典型化合物）的高活性和耐用催化剂，其金属纳米颗粒的尺寸和位置决定了催化活性和选择性。
