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氰基桥连同自旋铁（II）化合物中的自旋倾斜、变磁性和单链磁行为。

Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron(II) compound.

作者信息

Shao Dong, Zhang Shao-Liang, Zhao Xin-Hua, Wang Xin-Yi

机构信息

State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China.

出版信息

Chem Commun (Camb). 2015 Mar 14;51(21):4360-3. doi: 10.1039/c4cc10003d.

DOI:10.1039/c4cc10003d
PMID:25600433
Abstract

Spin canting, antiferromagnetic ordering, metamagnetism and single-chain magnetism were verified in a cyano-bridged Fe(II) compound synthesized from the pentagonal bipyramidal Fe(II) starting material in the presence of excessive BF4(-) anions.

摘要

在过量BF4(-)阴离子存在下，由五角双锥Fe(II)起始原料合成的氰基桥联Fe(II)化合物中，证实了自旋倾斜、反铁磁有序、变磁性和单链磁性。

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