Shao Dong, Zhang Shao-Liang, Zhao Xin-Hua, Wang Xin-Yi
State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China.
Chem Commun (Camb). 2015 Mar 14;51(21):4360-3. doi: 10.1039/c4cc10003d.
Spin canting, antiferromagnetic ordering, metamagnetism and single-chain magnetism were verified in a cyano-bridged Fe(II) compound synthesized from the pentagonal bipyramidal Fe(II) starting material in the presence of excessive BF4(-) anions.
在过量BF4(-)阴离子存在下,由五角双锥Fe(II)起始原料合成的氰基桥联Fe(II)化合物中,证实了自旋倾斜、反铁磁有序、变磁性和单链磁性。