Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
Nat Commun. 2015 Jan 20;6:5933. doi: 10.1038/ncomms6933.
Carbon dioxide exits in the atmosphere and is produced by the combustion of fossil fuels, the fermentation of sugars and the respiration of all living organisms. An active goal in organic synthesis is to take this carbon--trapped in a waste product--and re-use it to build useful chemicals. Recent advances in organometallic chemistry and catalysis provide effective means for the chemical transformation of CO₂ and its incorporation into synthetic organic molecules under mild conditions. Such a use of carbon dioxide as a renewable one-carbon (C1) building block in organic synthesis could contribute to a more sustainable use of resources.
二氧化碳存在于大气中,由化石燃料燃烧、糖发酵和所有生物的呼吸产生。在有机合成中,一个积极的目标是将这种被捕获在废物中的碳重新利用,用于构建有用的化学品。有机金属化学和催化的最新进展为在温和条件下将二氧化碳进行化学转化并将其纳入合成有机分子提供了有效的手段。在有机合成中,将二氧化碳作为可再生一碳(C1)构建块的这种利用,可以促进资源的更可持续利用。