Institute of Next Generation Matter Transformation, College of Chemical Engineering, and ‡College of Materials Science & Engineering, at Huaqiao University , 668 Jimei Boulevard, Xiamen, Fujian 361021, P. R. China.
Org Lett. 2015 Feb 6;17(3):516-9. doi: 10.1021/ol503472x. Epub 2015 Jan 22.
Copper-catalyzed aerobic oxidative esterification of acetophenones with alcohols using molecular oxygen has been developed to form a broad range of α-ketoesters in good yields. In addition to reporting scope and limitations of our new method, mechanism studies are reported that reveal that the carbonyl oxygen in the ester mainly originated from dioxygen.
铜催化的分子氧有氧氧化酯交换反应已被开发用于形成广泛的α-酮酯，具有良好的收率。除了报道我们新方法的范围和限制外，还报道了机理研究，表明酯中的羰基氧主要来源于氧气。
