College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072 (P. R. China) http://aiwenlei.whu.edu.cn/
Angew Chem Int Ed Engl. 2014 May 26;53(22):5657-61. doi: 10.1002/anie.201400612. Epub 2014 Apr 16.
A palladium-catalyzed oxidative carbonylative esterification of a variety of functionalized alcohols under base- and ligand-free conditions has been demonstrated. A CO/olefin combination was utilized as the acylating reagent with O2 as a benign oxidant. Notably, the scope of the substrate alcohols has been greatly broadened.
钯催化的各种功能化醇在无碱和无配体条件下的氧化羰基酯化反应已经得到了证明。采用 CO/烯烃组合作为酰化试剂，以 O2 作为温和氧化剂。值得注意的是，底物醇的适用范围得到了极大的拓宽。
