Ding Qing-Rong, Li Li-Ming, Zhang Lei, Zhang Jian
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
Inorg Chem. 2015 Feb 16;54(4):1209-11. doi: 10.1021/ic502895u. Epub 2015 Jan 23.
Two novel organic-inorganic hybrid frameworks containing multiarylpolycarboxylate linkers and cobalt phosphate layers, [H2DABCO]·[Co(HPO4)(bpdc)] (1) and [H2DABCO]3·[Co10(npa)3(PO4)6Cl2] (2), where bpdc = 4,4'-biphenyldicarboxylate, npa = 2,6-naphthalenedicarboxylate, and DABCO = 1,4-diazabicyclo[2.2.2]octane, have been solvothermally synthesized. Compound 1 features a 3D zeolite-like supramolecular network with ABW topology, and compound 2 is a 3D framework structure with unusual I(2)O(2) connectivity.
已通过溶剂热合成法制备出两种含有多芳基多羧酸盐连接体和磷酸钴层的新型有机-无机杂化骨架化合物，即[H₂DABCO]·[Co(HPO₄)(bpdc)] (1) 和[H₂DABCO]₃·[Co₁₀(npa)₃(PO₄)₆Cl₂] (2)，其中bpdc = 4,4'-联苯二甲酸，npa = 2,6-萘二甲酸，DABCO = 1,4-二氮杂双环[2.2.2]辛烷。化合物1具有ABW拓扑结构的三维类沸石超分子网络，化合物2是具有不寻常I(2)O(2)连接性的三维骨架结构。
