Kang Yao, Fang Wei-Hui, Zhang Lei, Zhang Jian
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
Chem Commun (Camb). 2015 May 28;51(43):8994-7. doi: 10.1039/c5cc02598b.
Two semiconductive cluster-organic frameworks based on Cu4I4 and Cu3I4 building units were obtained by the use of different organic structure-directing agents; the latter Cu3I4 nodes are tetrahedrally connected through 1,4-diazabicyclo[2.2.2]octane (DABCO) linkers and Cu-I bridges, giving rise to a zeolitic framework with SOD topology.
通过使用不同的有机结构导向剂，得到了两种基于Cu4I4和Cu3I4构建单元的半导电簇-有机框架；后者的Cu3I4节点通过1,4-二氮杂双环[2.2.2]辛烷（DABCO）连接体和Cu-I桥四面体连接，形成了具有SOD拓扑结构的沸石框架。
