Rasmussen Seth C, Evenson Sean J, McCausland Casey B
Department of Chemistry and Biochemistry, North Dakota State University, NDSU Dept. 2735, P.O. Box 6050, Fargo, ND 58108-6050, USA.
Chem Commun (Camb). 2015 Mar 18;51(22):4528-43. doi: 10.1039/c4cc09206f.
Although thiophene-based materials are among the most widely studied conjugated materials for a number of technological applications, most discussions of emissive conjugated materials have focused on other systems, primarily due to the lower emission quantum yields of thiophene-based systems. Over the last decade, however, this has begun to change with the development of new highly emissive thiophene-based materials. In this review, we provide an overview of fluorescent thiophene-based materials and their applications, highlighting in particular the various methods employed to achieve highly emissive materials, as well as a variety of reported applications including fluorescent biomarkers and organic light emitting diodes.
尽管基于噻吩的材料是众多技术应用中研究最为广泛的共轭材料之一,但关于发光共轭材料的大多数讨论都集中在其他体系上,主要是因为基于噻吩的体系的发射量子产率较低。然而,在过去十年中,随着新型高发光噻吩基材料的发展,这种情况开始发生变化。在本综述中,我们概述了基于噻吩的荧光材料及其应用,特别强调了用于实现高发光材料的各种方法,以及包括荧光生物标志物和有机发光二极管在内的各种已报道的应用。