Ronson Thomas O, Carney Jonathan R, Whitwood Adrian C, Taylor Richard J K, Fairlamb Ian J S
Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK.
Chem Commun (Camb). 2015 Feb 25;51(16):3466-9. doi: 10.1039/c4cc09810b.
Two novel succinimide-based palladium complexes, AsCat and FurCat, are highly efficient catalysts for room-temperature Stille cross-coupling of organostannanes with benzyl chlorides. The air- and moisture-stable catalysts are prepared in one step, and the coupling reactions proceed with a high selectivity for the benzyl position under mild conditions without the need for additives.
两种新型的基于琥珀酰亚胺的钯配合物AsCat和FurCat，是用于有机锡烷与苄基氯在室温下进行Stille交叉偶联的高效催化剂。这些对空气和湿气稳定的催化剂一步制备而成，并且偶联反应在温和条件下对苄基位置具有高选择性地进行，无需添加剂。
