Cornil Johan, Echeverria Pierre-Georges, Phansavath Phannarath, Ratovelomanana-Vidal Virginie, Guérinot Amandine, Cossy Janine
Laboratoire de Chimie Organique, Institute of Chemistry, Biology and Innovation (CBI)-UMR 8231, ESPCI ParisTech, CNRS , , 10 rue Vauquelin 75231 Paris Cedex 05, France.
Org Lett. 2015 Feb 20;17(4):948-51. doi: 10.1021/acs.orglett.5b00042. Epub 2015 Feb 2.
A simple Heck coupling between an alkenyl iodo-boronate and a variety of terminal olefins is disclosed. This method gives access to a wide range of dienic moieties including valuable bis-functionalized dienes. The synthetic potential of the coupling reaction is demonstrated by a short and modular preparation of several tetraenic compounds.
公开了一种烯基碘硼酸酯与多种末端烯烃之间简单的Heck偶联反应。该方法可用于制备多种二烯基部分，包括有价值的双官能化二烯。通过几种四烯化合物的简短且模块化的制备，证明了该偶联反应的合成潜力。
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