Zhao Leihong, Shen Liguo, He Yiming, Hong Huachang, Lin Hongjun
College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004, PR China; Institute of Physical Chemistry, Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Zhejiang Normal University, Jinhua 321004, PR China.
College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004, PR China.
J Colloid Interface Sci. 2015 May 15;446:84-90. doi: 10.1016/j.jcis.2015.01.009. Epub 2015 Jan 13.
In this study, the interfacial interactions between sludge flocs and a rough membrane surface in a submerged membrane bioreactor were investigated. Models describing these interfacial interactions were firstly proposed based on the surface element integration (SEI) method. Surface properties of sludge flocs and membrane were experimentally determined to simulate the models through composite Simpson's rule. It was found that, roughness on membrane surface significantly decreased interaction strength, which enabled the sludge flocs to more easily attach on and detach from the rough membrane surface. Further analysis showed that the value of total interaction energy increased with asperity radius, while the strength of total interaction energy decreased with asperity height. Results also demonstrated that increase in floc size would significantly decrease the attractive specific total interaction with rough membrane surface. It was revealed that there existed a critical asperity radius above which the total interaction energy in certain separation distance coverage was continuously repulsive, facilitating membrane fouling control in MBRs. This study demonstrated the possibility to mitigate membrane fouling by "tailoring" membrane surface roughness.
在本研究中,对浸没式膜生物反应器中污泥絮体与粗糙膜表面之间的界面相互作用进行了研究。首先基于表面元积分(SEI)方法提出了描述这些界面相互作用的模型。通过复合辛普森法则实验测定了污泥絮体和膜的表面性质以模拟模型。结果发现,膜表面的粗糙度显著降低了相互作用强度,这使得污泥絮体能够更轻松地附着在粗糙膜表面并从其分离。进一步分析表明,总相互作用能的值随粗糙峰半径的增加而增加,而总相互作用能的强度随粗糙峰高度的增加而降低。结果还表明,絮体尺寸的增加会显著降低与粗糙膜表面的吸引性比总相互作用。研究发现存在一个临界粗糙峰半径,超过该半径,在一定分离距离范围内的总相互作用能持续为排斥力,这有助于控制膜生物反应器中的膜污染。本研究证明了通过“调整”膜表面粗糙度来减轻膜污染的可能性。