Yan Sheng-Yi, Liu Yue-Jin, Liu Bin, Liu Yan-Hua, Shi Bing-Feng
Department of Chemistry, Zhejiang University, Hangzhou 310027, China.
Chem Commun (Camb). 2015 Mar 7;51(19):4069-72. doi: 10.1039/c4cc10446c.
A nickel-catalyzed thiolation of unactivated C(sp(2))-H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. The reaction tolerates various important functional groups and heteroarenes, providing an efficient synthetic pathway to access diverse diaryl sulfides.
描述了一种使用PIP导向基团，通过镍催化未活化的C(sp(2))-H键与二硫化物进行硫醇化反应的方法。该过程使用催化量的镍催化剂，无需金属氧化剂或共催化剂。该反应能耐受各种重要的官能团和杂芳烃，为合成各种二芳基硫醚提供了一条有效的途径。
Zotero 插件