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外部场中无标度聚合物网络的流体动力学效应。

Hydrodynamic effects on scale-free polymer networks in external fields.

作者信息

Galiceanu M

机构信息

Departamento de Física, Universidade Federal do Amazonas, 69077-000 Manaus, Brazil.

出版信息

J Chem Phys. 2014 Jan 21;140(3):034901. doi: 10.1063/1.4861218.

Abstract

We numerically analyze the influence of hydrodynamic interactions (HI) on scale-free polymer networks under external forces. We envisage that these polymer networks move under external applied fields: mechanical or electrical type. We work in the framework of the bead-spring model and include the HI in a preaveraged Oseen manner. We focus on physical quantities which depend on the eigenvalue spectrum: averaged monomer displacement and the mechanical relaxation modulus with its two components: the storage and the loss modulus. We analyze how these quantities depend on the underlying topology, such as the number of monomers and γ, which is the parameter that measures the connectivity of a network. The influence of topology appears in the intermediate region of time or frequency. For intermediate time/frequency region we do not encounter regions of constant slope by considering the hydrodynamic interactions, differently from the Rouse model, which neglects these HI. As expected we observe a more linear-like topology for high values of γ and a more star-like shape for low γs.

摘要

我们数值分析了流体动力学相互作用(HI)在外力作用下对无标度聚合物网络的影响。我们设想这些聚合物网络在外部施加场(机械或电类型)下移动。我们在珠簧模型的框架内进行研究,并以预平均奥森方式纳入HI。我们关注依赖于本征值谱的物理量:平均单体位移以及具有两个分量(储能模量和损耗模量)的机械松弛模量。我们分析这些量如何依赖于基础拓扑结构,例如单体数量和γ,γ是衡量网络连通性的参数。拓扑结构的影响出现在时间或频率的中间区域。对于中间时间/频率区域,与忽略这些HI的劳厄模型不同,考虑流体动力学相互作用时我们不会遇到恒定斜率的区域。正如预期的那样,对于高γ值我们观察到更类似线性的拓扑结构,而对于低γ值则观察到更类似星状的形状。

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