• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

含铜小孔沸石及类沸石上甲烷向甲醇的转化

Conversion of methane to methanol on copper-containing small-pore zeolites and zeotypes.

作者信息

Wulfers M J, Teketel S, Ipek B, Lobo R F

机构信息

Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA.

出版信息

Chem Commun (Camb). 2015 Mar 14;51(21):4447-50. doi: 10.1039/c4cc09645b.

DOI:10.1039/c4cc09645b
PMID:25679753
Abstract

This communication reports the discovery of several small-pore Cu-zeolites and zeotypes that produce methanol from methane and water vapor, and produce more methanol per copper atom than Cu-ZSM-5 and Cu-mordenite. The new materials include Cu-SSZ-13, Cu-SSZ-16, Cu-SSZ-39, and Cu-SAPO-34.

摘要

本通讯报道了几种小孔径铜沸石和类沸石的发现,这些材料可由甲烷和水蒸气制得甲醇,且每个铜原子生成的甲醇比Cu-ZSM-5和铜丝光沸石更多。新材料包括Cu-SSZ-13、Cu-SSZ-16、Cu-SSZ-39和Cu-SAPO-34。

相似文献

1
Conversion of methane to methanol on copper-containing small-pore zeolites and zeotypes.含铜小孔沸石及类沸石上甲烷向甲醇的转化
Chem Commun (Camb). 2015 Mar 14;51(21):4447-50. doi: 10.1039/c4cc09645b.
2
Catalytic conversion of methane to methanol on Cu-SSZ-13 using NO as oxidant.
Chem Commun (Camb). 2016 Nov 8;52(91):13401-13404. doi: 10.1039/c6cc07893a.
3
Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites.通过负载在ZSM-5和丝光沸石上的双(μ-氧)二铜核实现甲烷的选择性氧化。
J Am Chem Soc. 2005 Feb 9;127(5):1394-5. doi: 10.1021/ja047158u.
4
Continuous Partial Oxidation of Methane to Methanol Catalyzed by Diffusion-Paired Copper Dimers in Copper-Exchanged Zeolites.铜交换沸石中扩散偶联的铜二聚体催化甲烷连续部分氧化制甲醇。
J Am Chem Soc. 2019 Jul 24;141(29):11641-11650. doi: 10.1021/jacs.9b04906. Epub 2019 Jul 15.
5
A comparison of copper and acid site zeolites for the production of nitric oxide for biomedical applications.铜基和酸基沸石在生物医学应用中用于生产一氧化氮的比较。
Dalton Trans. 2017 Mar 21;46(12):3915-3920. doi: 10.1039/c7dt00195a.
6
Economical way to synthesize SSZ-13 with abundant ion-exchanged Cu+ for an extraordinary performance in selective catalytic reduction (SCR) of NOx by ammonia.用经济的方法合成具有丰富离子交换 Cu+ 的 SSZ-13,在氨选择性催化还原(SCR)NOx 中表现出非凡的性能。
Environ Sci Technol. 2014 Dec 2;48(23):13909-16. doi: 10.1021/es503707c. Epub 2014 Nov 18.
7
Methane to acetic acid over Cu-exchanged zeolites: mechanistic insights from a site-specific carbonylation reaction.铜交换沸石上甲烷制乙酸:位点特异性羰基化反应的机理见解
J Am Chem Soc. 2015 Feb 11;137(5):1825-32. doi: 10.1021/ja5106927. Epub 2015 Feb 2.
8
Exploring the Impact of Active Site Structure on the Conversion of Methane to Methanol in Cu-Exchanged Zeolites.探索活性位点结构对铜交换沸石中甲烷转化为甲醇的影响。
Angew Chem Int Ed Engl. 2024 Jun 3;63(23):e202403179. doi: 10.1002/anie.202403179. Epub 2024 Apr 30.
9
Correlation of the changes in the framework and active Cu sites for typical Cu/CHA zeolites (SSZ-13 and SAPO-34) during hydrothermal aging.典型Cu/CHA沸石(SSZ-13和SAPO-34)在水热老化过程中骨架和活性铜位点变化的相关性。
Phys Chem Chem Phys. 2015 Nov 21;17(43):29142-9. doi: 10.1039/c5cp05128b.
10
The Effect of the Active-Site Structure on the Activity of Copper Mordenite in the Aerobic and Anaerobic Conversion of Methane into Methanol.活性位点结构对丝光沸石铜在甲烷有氧和厌氧转化为甲醇过程中活性的影响。
Angew Chem Int Ed Engl. 2018 Jul 16;57(29):8906-8910. doi: 10.1002/anie.201802922. Epub 2018 Jun 19.

引用本文的文献

1
Elucidation of the Structure-Activity Relationship for Cu-Erionite in the Direct Conversion of Methane to Methanol: An Operando XAS Study.甲烷直接转化为甲醇过程中铜-毛沸石结构-活性关系的阐明:原位X射线吸收光谱研究
J Am Chem Soc. 2025 Aug 13;147(32):28723-28734. doi: 10.1021/jacs.5c03554. Epub 2025 Jun 20.
2
Direct Methane to Methanol Conversion: An Overview of Non-Syn Gas Catalytic Strategies.直接甲烷制甲醇转化:非合成气催化策略概述
Chem Rec. 2025 Jan 16;25(2):e202400186. doi: 10.1002/tcr.202400186.
3
Competition between Mononuclear and Binuclear Copper Sites across Different Zeolite Topologies.
不同沸石拓扑结构中单核和双核铜位点之间的竞争
JACS Au. 2024 Jan 4;4(1):197-215. doi: 10.1021/jacsau.3c00632. eCollection 2024 Jan 22.
4
Understanding C-H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments.通过结合先进光谱学和程序升温还原实验理解铜-丝光沸石上轻质烷烃中的碳-氢活化
Chem Sci. 2023 Aug 22;14(36):9704-9723. doi: 10.1039/d3sc01677c. eCollection 2023 Sep 20.
5
Leaching Stability and Redox Activity of Copper-MFI Zeolites Prepared by Solid-State Transformations: Comparison with Ion-Exchanged and Impregnated Samples.通过固态转化制备的铜-MFI沸石的浸出稳定性和氧化还原活性:与离子交换和浸渍样品的比较
Materials (Basel). 2023 Jan 10;16(2):671. doi: 10.3390/ma16020671.
6
Methane Oxidation to Methanol.甲烷氧化制甲醇。
Chem Rev. 2023 May 10;123(9):6359-6411. doi: 10.1021/acs.chemrev.2c00439. Epub 2022 Dec 2.
7
Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites.离子迁移率对沸石中铜离子的氧化还原和催化性能的影响。
Chem Sci. 2022 Aug 19;13(35):10238-10250. doi: 10.1039/d2sc03565k. eCollection 2022 Sep 14.
8
Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion.用于甲烷制甲醇转化的铜交换大孔和小孔丝光沸石(MOR)
RSC Adv. 2021 Sep 20;11(49):31058-31061. doi: 10.1039/d1ra04643h. eCollection 2021 Sep 14.
9
Harnessing of Diluted Methane Emissions by Direct Partial Oxidation of Methane to Methanol over Cu/Mordenite.通过在铜/丝光沸石上直接将甲烷部分氧化为甲醇来利用稀释的甲烷排放物。
Ind Eng Chem Res. 2021 Jul 7;60(26):9409-9417. doi: 10.1021/acs.iecr.1c01069. Epub 2021 Jun 24.
10
Role of catalytic nitrile decomposition in tricopper complex mediated direct partial oxidation of methane to methanol.催化腈分解在三铜配合物介导的甲烷直接部分氧化制甲醇中的作用。
Sci Rep. 2021 Sep 28;11(1):19175. doi: 10.1038/s41598-021-98721-2.