Wulfers M J, Teketel S, Ipek B, Lobo R F
Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA.
Chem Commun (Camb). 2015 Mar 14;51(21):4447-50. doi: 10.1039/c4cc09645b.
This communication reports the discovery of several small-pore Cu-zeolites and zeotypes that produce methanol from methane and water vapor, and produce more methanol per copper atom than Cu-ZSM-5 and Cu-mordenite. The new materials include Cu-SSZ-13, Cu-SSZ-16, Cu-SSZ-39, and Cu-SAPO-34.
本通讯报道了几种小孔径铜沸石和类沸石的发现,这些材料可由甲烷和水蒸气制得甲醇,且每个铜原子生成的甲醇比Cu-ZSM-5和铜丝光沸石更多。新材料包括Cu-SSZ-13、Cu-SSZ-16、Cu-SSZ-39和Cu-SAPO-34。