A metal-enhanced fluorescence sensing platform based on new mercapto rhodamine derivatives for reversible Hg(2+) detection.

A new metal-enhanced fluorescence (MEF) chemosensor HMS-Ag-R-2SH for Hg(2+) has been prepared via a simple and effective method. The fluorescent chemosensor was based on a mercapto rhodamine derivatives linked with Ag nanoparticles, and the Ag nanoparticles were supported on hexagonal mesoporous silica material (HMS). Transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), absorption spectroscopy and fluorescence spectroscopy techniques were employed to characterize morphology, mesostructure and spectral features of the chemosensor. This chemosensor works in a nearly pure aqueous solution with a broad pH range. The output signals include color change and fluorescence. Moreover, HMS-Ag-R-2SH presents excellent anti-disturbance ability when exposed to a series of competitive cations such as Ag(+), K(+), Li(+), Na(+), Ba(2+), Ca(2+), Cd(2+), Co(2+), Cu(2+), Mg(2+), Mn(2+), Ni(2+), Pb(2+), Zn(2+), Al(3+), Cr(3+) and Fe(3+). The selectivity of this chemosensor was significantly improved due to the introduction of the sulphydryl. The chemosensor showed a lower detection limit of 2.1ppb for Hg(2+). Importantly, HMS-Ag-R-2SH could be regenerated with sodium sulfide solution for several cycles and maintain a high sensitivity.