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一种基于罗丹明6G且具有两步反应机制的汞荧光比色化学传感器。

A Fluorescent and Colorimetric Chemosensor for Hg Based on Rhodamine 6G With a Two-Step Reaction Mechanism.

作者信息

Bai Cui-Bing, Wang Wei-Gang, Zhang Jie, Wang Chang, Qiao Rui, Wei Biao, Zhang Lin, Chen Shui-Sheng, Yang Song

机构信息

School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang, China.

Anhui Province Key Laboratory for Degradation and Monitoring of Pollution of the Environment, Fuyang, China.

出版信息

Front Chem. 2020 Feb 19;8:14. doi: 10.3389/fchem.2020.00014. eCollection 2020.

Abstract

A fluorescent and colorimetric chemosensor based on rhodamine 6G was designed, synthesized, and characterized. Based on a two-step reaction, the chemosensor effectively recognized Hg. The interaction between the chemosensor and Hg was confirmed by ultraviolet-visible spectrophotometry, fluorescence spectroscopy, electrospray ionization-mass spectrometry, Fourier-transform infrared spectroscopy, and frontier molecular orbital calculations. The chemosensor was also incorporated into test strips and silica gel plates, which demonstrated good selectivity and high sensitivity for Hg.

摘要

设计、合成并表征了一种基于罗丹明6G的荧光和比色化学传感器。基于两步反应,该化学传感器能有效识别汞。通过紫外可见分光光度法、荧光光谱法、电喷雾电离质谱法、傅里叶变换红外光谱法和前线分子轨道计算,证实了化学传感器与汞之间的相互作用。该化学传感器还被整合到测试条和硅胶板中,对汞表现出良好的选择性和高灵敏度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e93b/7042397/8e5c702a503b/fchem-08-00014-g0001.jpg

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