Pawsey Anne C, Clegg Paul S
SUPA, School of Physics and Astronomy, JCMB, Mayfield Road, Edinburgh, EH9 3JZ, UK.
Soft Matter. 2015 May 7;11(17):3304-12. doi: 10.1039/c4sm02131b.
We study the effect of disorder on the phase transitions of a system already dominated by defects. Micron-sized colloidal particles are dispersed chiral nematic liquid crystals which exhibit a blue phase (BP). The colloids are a source of disorder, disrupting the liquid crystal as the system is heated from the cholesteric to the isotropic phase through the blue phase. The colloids act as a preferential site for the growth of BPI from the cholesteric; in high chirality samples BPII also forms. In both BPI and BPII the colloids lead to localised melting to the isotropic, giving rise to faceted isotropic inclusions. This is in contrast to the behaviour of a cholesteric LC where colloids lead to system spanning defects.
我们研究了无序对一个已经由缺陷主导的系统相变的影响。微米级的胶体颗粒分散在呈现蓝相(BP)的手性向列型液晶中。这些胶体是无序的来源,当系统从胆甾相通过蓝相加热到各向同性相时,会扰乱液晶。这些胶体充当了从胆甾相生长出蓝相I(BPI)的优先位点;在高螺旋度样品中也会形成蓝相II(BPII)。在BPI和BPII中,胶体都会导致局部熔化到各向同性相,产生多面的各向同性夹杂物。这与胆甾型液晶的行为形成对比,在胆甾型液晶中胶体会导致贯穿整个系统的缺陷。