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Crystal structure of 4,4'-(ethane-1,2-di-yl)bis-(2,6-di-bromo-aniline).

作者信息

Hauptvogel Ines, Seichter Wilhelm, Weber Edwin

机构信息

Institut für Organische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachsen, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):97-9. doi: 10.1107/S2056989014027182.

DOI:10.1107/S2056989014027182
PMID:25705462
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4331912/
Abstract

In the title compound, C14H12Br4N2, the mol-ecule lies across an inversion center and hence the benzene rings are strictly coplanar. In the crystal, mol-ecules are linked by N-H⋯N and weak N-H⋯Br hydrogen bonds, forming a two-dimensional network parallel to (101). In addition, type II Br⋯Br inter-actions [3.625 (4) Å] complete a three-dimensional supra-molecular network.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c606/4331912/989640b64525/e-71-00097-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c606/4331912/b8680ab094b6/e-71-00097-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c606/4331912/989640b64525/e-71-00097-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c606/4331912/b8680ab094b6/e-71-00097-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c606/4331912/989640b64525/e-71-00097-fig2.jpg

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本文引用的文献

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Angew Chem Int Ed Engl. 2009;48(40):7298-332. doi: 10.1002/anie.200806339.
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A short history of SHELX.SHELX简史。
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Designed synthesis of 3D covalent organic frameworks.三维共价有机框架的设计合成
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