Department of Physics, University of Washington, Seattle, Washington 98195, USA.
Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195, USA.
Nat Commun. 2015 Feb 24;6:6242. doi: 10.1038/ncomms7242.
Van der Waals bound heterostructures constructed with two-dimensional materials, such as graphene, boron nitride and transition metal dichalcogenides, have sparked wide interest in device physics and technologies at the two-dimensional limit. One highly coveted heterostructure is that of differing monolayer transition metal dichalcogenides with type-II band alignment, with bound electrons and holes localized in individual monolayers, that is, interlayer excitons. Here, we report the observation of interlayer excitons in monolayer MoSe2-WSe2 heterostructures by photoluminescence and photoluminescence excitation spectroscopy. We find that their energy and luminescence intensity are highly tunable by an applied vertical gate voltage. Moreover, we measure an interlayer exciton lifetime of ~1.8 ns, an order of magnitude longer than intralayer excitons in monolayers. Our work demonstrates optical pumping of interlayer electric polarization, which may provoke further exploration of interlayer exciton condensation, as well as new applications in two-dimensional lasers, light-emitting diodes and photovoltaic devices.
范德华异质结构由二维材料构建,如石墨烯、氮化硼和过渡金属二卤化物,在二维极限的器件物理和技术方面引起了广泛的兴趣。一种备受追捧的异质结是具有 II 型能带排列的不同单层过渡金属二卤化物,其束缚电子和空穴定域在单个单层中,即层间激子。在这里,我们通过光致发光和光致发光激发光谱报告了在单层 MoSe2-WSe2 异质结构中观察到的层间激子。我们发现它们的能量和发光强度可以通过施加的垂直栅极电压高度可调。此外,我们测量了~1.8 ns 的层间激子寿命,比单层中的层内激子长一个数量级。我们的工作证明了层间电极化的光泵浦,这可能会引发对层间激子凝聚的进一步探索,以及在二维激光、发光二极管和光伏器件中的新应用。
Nano Lett. 2017-1-4
Nano Lett. 2024-9-25
Science. 2016-2-12
J Phys Chem Lett. 2025-8-14
J Phys Chem Lett. 2025-7-10
ACS Appl Mater Interfaces. 2025-7-9
ACS Photonics. 2025-5-29
Nanophotonics. 2025-3-11
Proc Natl Acad Sci U S A. 2025-5-6