外围取代：调节四（酞菁基）镝（III）单分子磁体磁行为的简便方法。
Peripheral substitution: an easy way to tuning the magnetic behavior of tetrakis(phthalocyaninato) dysprosium(III) SMMs.
作者信息
Shang Hong, Zeng Suyuan, Wang Hailong, Dou Jianmin, Jiang Jianzhuang
机构信息
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China.
Department of Chemistry, Liaocheng University, Liaocheng 252059, China.
出版信息
Sci Rep. 2015 Mar 6;5:8838. doi: 10.1038/srep08838.
Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and controlling the molecular structure and in turn the magnetic properties of tetrakis(tetrapyrrole) lanthanide SMMs through simple tetrapyrrole peripheral substitution.
两种具有不同酞菁外周取代程度、因而Dy离子具有不同配位几何结构的四（酞菁基）镝（III）-镉（II）单分子磁体（SMMs）被发现表现出不同的SMM行为，这提供了一种通过简单的四吡咯外周取代来调节和控制四（四吡咯）镧系SMMs的分子结构进而磁性能的简便方法。
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