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氮掺杂石墨层包裹的钴纳米粒子在碱性介质中作为高效氧还原催化剂。

N-doped graphitic layer encased cobalt nanoparticles as efficient oxygen reduction catalysts in alkaline media.

机构信息

Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.

出版信息

Nanoscale. 2015 Mar 19;7(13):5607-11. doi: 10.1039/c4nr07571d.

DOI:10.1039/c4nr07571d
PMID:25751169
Abstract

Nitrogen doped graphitic layer encased cobalt (N-C@Co) nanoparticles, as novel non-precious-metal catalysts for the oxygen reduction reaction (ORR), were fabricated by a facile method using cyanamide and cobalt nitrate as precursors. The N-C@Co catalysts exhibited comparable catalytic performance, better stability and improved methanol tolerance towards the ORR than those of the commercial Pt/C catalyst.

摘要

氮掺杂石墨层包裹的钴(N-C@Co)纳米粒子作为新型非贵金属氧还原反应(ORR)催化剂,通过简便的方法,以氰胺和硝酸钴为前驱体制备。与商业 Pt/C 催化剂相比,N-C@Co 催化剂对 ORR 具有相当的催化性能、更好的稳定性和提高的甲醇耐受性。

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引用本文的文献

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synthesis of metal embedded nitrogen doped carbon nanotubes as an electrocatalyst for the oxygen reduction reaction with high activity and stability.金属嵌入氮掺杂碳纳米管的合成作为用于氧还原反应的具有高活性和稳定性的电催化剂。
RSC Adv. 2018 Jul 12;8(44):25051-25056. doi: 10.1039/c8ra03139h. eCollection 2018 Jul 9.
2
Core@shell structured Co-CoO@NC nanoparticles supported on nitrogen doped carbon with high catalytic activity for oxygen reduction reaction.负载在氮掺杂碳上的核壳结构Co-CoO@NC纳米颗粒对氧还原反应具有高催化活性。
RSC Adv. 2018 Apr 18;8(26):14462-14472. doi: 10.1039/c8ra01680a. eCollection 2018 Apr 17.
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Laser-Assisted Production of Carbon-Encapsulated Pt-Co Alloy Nanoparticles for Preferential Oxidation of Carbon Monoxide.
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