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用于轻质烃吸附与分离的阴离子金属有机框架材料。

Anionic metal-organic framework for adsorption and separation of light hydrocarbons.

作者信息

Li Jia, Fu Hong-Ru, Zhang Jian, Zheng Lan-Sun, Tao Jun

机构信息

†State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.

‡Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, People's Republic of China.

出版信息

Inorg Chem. 2015 Apr 6;54(7):3093-5. doi: 10.1021/acs.inorgchem.5b00316. Epub 2015 Mar 24.

DOI:10.1021/acs.inorgchem.5b00316
PMID:25802987
Abstract

The reaction of nickel(II) sulfate with 4,4',4"-s-triazine-2,4,6-triyltribenzoate in dimethyl sulfoxide afforded a hexanuclear nickel(II)-based anionic 2-fold interpenetrated metal-organic framework exhibiting the ability to adsorb and separate light hydrocarbons and canted antiferromagnetism.

摘要

硫酸镍(II)与4,4',4''-均三嗪-2,4,6-三苯甲酸酯在二甲基亚砜中的反应得到了一种基于六核镍(II)的阴离子型2重互穿金属有机骨架,该骨架表现出吸附和分离轻质烃类的能力以及倾斜反铁磁性。

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