异岩芹醇：来自海七鳃鳗（Petromyzon marinus）的新型二羟基化四氢呋喃对映体。
Iso-petromyroxols: novel dihydroxylated tetrahydrofuran enantiomers from sea lamprey (Petromyzon marinus).
作者信息
Li Ke, Brant Cory O, Bussy Ugo, Pinnamaneni Harshita, Patel Hinal, Hoye Thomas R, Li Weiming
机构信息
Department of Fisheries and Wildlife, Michigan State University, East Lansing, MI 48824, USA.
Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
出版信息
Molecules. 2015 Mar 23;20(3):5215-22. doi: 10.3390/molecules20035215.
An enantiomeric pair of new fatty acid-derived hydroxylated tetrahydrofurans, here named iso-petromyroxols, were isolated from sea lamprey larvae-conditioned water. The relative configuration of iso-petromyroxol was elucidated with 1D and 2D NMR spectroscopic analyses. The ratio of enantiomers (er) in the natural sample was measured by chiral-HPLC-MS/MS to be ca. 3:1 of (-)- to (+)-antipodes.
从七鳃鳗幼体条件培养液中分离出一对对映体形式的新型脂肪酸衍生羟基化四氢呋喃，在此命名为异岩芹醇。通过一维和二维核磁共振光谱分析阐明了异岩芹醇的相对构型。采用手性高效液相色谱-串联质谱法测定天然样品中对映体比例（er），（-）-对映体与（+）-对映体的比例约为3:1。
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