芘稠合苝二亚胺：合成、表征及其在高性能有机场效应晶体管和光学限幅中的应用
Pyrene fused perylene diimides: synthesis, characterization and applications in organic field-effect transistors and optical limiting with high performance.
作者信息
Zhan Xuejun, Zhang Ji, Tang Sheng, Lin Yuxuan, Zhao Min, Yang Jie, Zhang Hao-Li, Peng Qian, Yu Gui, Li Zhen
机构信息
Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan, 430072, China.
出版信息
Chem Commun (Camb). 2015 Apr 28;51(33):7156-9. doi: 10.1039/c5cc00966a.
Three pyrene fused PDI derivatives have been obtained, in which totally different properties were observed when adopting different fusing types. For bilaterally benzannulated PDIs, through spin-coating, bottom-contact OFET devices exhibited a p-type mobility up to 1.13 cm(2) V(-1) s(-1), with an on/off ratio of 10(8) in air.
已获得三种芘稠合的苝二酰亚胺衍生物，当采用不同的稠合类型时，观察到了完全不同的性质。对于双边苯并稠合的苝二酰亚胺，通过旋涂法制备的底接触有机场效应晶体管器件呈现出高达1.13 cm² V⁻¹ s⁻¹的p型迁移率，在空气中的开/关比为10⁸。
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