结构源自TiO(OR)(OOCR')的混合金属氧簇
Mixed-Metal Oxo Clusters Structurally Derived from TiO(OR)(OOCR').
作者信息
Artner Christine, Koyun Ayse, Czakler Matthias, Schubert Ulrich
机构信息
Institute of Materials Chemistry, Vienna University of Technology Getreidemarkt 9, 1060 Vienna, Austria.
出版信息
Eur J Inorg Chem. 2014 Oct;2014(29):5008-5014. doi: 10.1002/ejic.201402499. Epub 2014 Aug 15.
The mixed-metal oxo clusters FeTiO(OPr)(OMc) (OMc = methacrylate), ZnTiO(OPr)(OMc), CdTiO(OAc)(OMc)(HOPr), [CaTiO(OAc)(OMc)] , and [SrTiO(OMc)(HOMc)] were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition TiO(OR)(OOCR'). The Ca and Sr derivatives consist of chains of condensed clusters.
通过钛醇盐与相应的金属醋酸盐和甲基丙烯酸反应，得到了混合金属氧簇FeTiO(OPr)(OMc)（OMc = 甲基丙烯酸酯）、ZnTiO(OPr)(OMc)、CdTiO(OAc)(OMc)(HOPr)、[CaTiO(OAc)(OMc)] 和[SrTiO(OMc)(HOMc)] 。它们的结构源自组成TiO(OR)(OOCR')的钛簇。钙和锶的衍生物由缩合簇链组成。
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