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含有膦酸酯和甲基丙烯酸酯配体的钛氧/烷氧基簇合物。

Titanium oxo/alkoxo clusters with both phosphonate and methacrylate ligands.

作者信息

Czakler Matthias, Artner Christine, Schubert Ulrich

机构信息

Institute of Materials Chemistry, Vienna University of Technology, Vienna, Austria.

出版信息

Monatsh Chem. 2015;146(8):1249-1256. doi: 10.1007/s00706-015-1444-5. Epub 2015 Apr 8.

DOI:10.1007/s00706-015-1444-5
PMID:26190863
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4498291/
Abstract

ABSTRACT

The clusters TiO(OPr)(OMc)(OPR) (OMc = methacrylate; R = Et, CHCHCHBr) and Ti(OPr)(OMc)(OPCHCH=CH) were obtained when Ti(OPr) was reacted with the corresponding bis(trimethylsilyl) phosphonate and methacrylic acid. Oxo clusters of the composition TiO(OPr)(OMc)(OPR), with a variety of groups R (Et, Ph, CH=CH, CHPh, CHCH=CH, CHCHCHBr, CHCHCN, CHC(O)Me, CHCHOC(O)C(Me)=CH), were formed instead, when a stoichiometric amount of water was added to the reaction mixture.

摘要

摘要

当Ti(OPr)与相应的双(三甲基甲硅烷基)膦酸酯和甲基丙烯酸反应时，得到了簇合物TiO(OPr)(OMc)(OPR)（OMc = 甲基丙烯酸酯；R = 乙基、CHCHCHBr）和Ti(OPr)(OMc)(OPCHCH=CH)。相反，当向反应混合物中加入化学计量的水时，会形成组成TiO(OPr)(OMc)(OPR)的氧簇，其中R有多种基团（乙基、苯基、CH=CH、CHPh、CHCH=CH、CHCHCHBr、CHCHCN、CHC(O)Me、CHCHOC(O)C(Me)=CH）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/f34522ea2292/706_2015_1444_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/b380b538c6c0/706_2015_1444_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/2b51529a1ea3/706_2015_1444_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/d35ee2da25c2/706_2015_1444_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/f34522ea2292/706_2015_1444_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/b380b538c6c0/706_2015_1444_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/2b51529a1ea3/706_2015_1444_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/d35ee2da25c2/706_2015_1444_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b005/4498291/f34522ea2292/706_2015_1444_Sch1_HTML.jpg

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本文引用的文献

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Eur J Inorg Chem. 2014 Apr;2014(12):2038-2045. doi: 10.1002/ejic.201400051. Epub 2014 Mar 11.
2
Molecular transition-metal phosphonates.分子过渡金属膦酸盐。
Dalton Trans. 2011 May 28;40(20):5394-418. doi: 10.1039/c0dt01069c. Epub 2011 Mar 3.
3
Cluster-based inorganic-organic hybrid materials.基于簇的无机-有机杂化材料。
含有双齿和三齿有机配体的钛氧簇：结构从小型到大型的逐步演变
Chemistry. 2021 Aug 5;27(44):11239-11256. doi: 10.1002/chem.202101287. Epub 2021 Jun 29.
Chem Soc Rev. 2011 Feb;40(2):575-82. doi: 10.1039/c0cs00009d. Epub 2010 Sep 28.
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Metal alkoxides as versatile precursors for group 4 phosphonates: synthesis and X-ray structure of a novel organosoluble zirconium phosphonate.金属醇盐作为第4族膦酸盐的通用前驱体：一种新型有机可溶性锆膦酸盐的合成与X射线结构
Inorg Chem. 2000 Jan 10;39(1):23-6. doi: 10.1021/ic9907361.
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Syntheses, characterizations, and single-crystal X-ray structures of soluble titanium alkoxide phosphonates.可溶性烷氧基钛膦酸盐的合成、表征及单晶X射线结构
Inorg Chem. 2000 Jul 24;39(15):3325-32. doi: 10.1021/ic000002k.