State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 13002 (China); University of Chinese Academy of Sciences, Beijing, 100049 (China).
Angew Chem Int Ed Engl. 2015 May 11;54(20):5994-8. doi: 10.1002/anie.201501195. Epub 2015 Mar 27.
Reported are two highly efficient metal-free perylene dyes featuring N-annulated thienobenzoperylene (NTBP) and N-annulated thienocyclopentaperylene (NTCP), which are coplanar polycyclic aromatic hydrocarbons. Without the use of any coadsorbate, the metal-free organic dye derived from the NTCP segment was used for a dye-sensitized solar cell which attained a power conversion efficiency of 12% under an irradiance of 100 mW cm(-2), simulated air mass global (AM1.5G) sunlight.
报告了两种高效的无金属苝染料，其特征为 N-稠合噻吩并苯并苝（NTBP）和 N-稠合噻吩并环戊并苝（NTCP），它们是共面多环芳烃。在不使用任何共吸附剂的情况下，源自 NTCP 片段的无金属有机染料被用于染料敏化太阳能电池，在 100 mW cm(-2)、模拟大气全球（AM1.5G）阳光辐照下，该电池达到了 12%的功率转换效率。
